Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Imaging of Chemical Kinetics at the Water–Water Interface in a Free-Flowing Liquid Flat-Jet
 
research article

Imaging of Chemical Kinetics at the Water–Water Interface in a Free-Flowing Liquid Flat-Jet

Schewe, H. Christian
•
Credidio, Bruno
•
Ghrist, Aaron M.
Show more
April 26, 2022
Journal of the American Chemical Society

We present chemical kinetics measurements of the luminol oxidation chemiluminescence (CL) reaction at the interface between two aqueous solutions, using liquid jet technology. Free-flowing liquid microjets are a relatively recent development that have found their way into a growing number of applications in spectroscopy and dynamics. A variant thereof, called flat-jet, is obtained when two cylindrical jets of a liquid are crossed, leading to a chain of planar leaf-shaped structures of the flowing liquid. We here show that in the first leaf of this chain, the fluids do not exhibit turbulent mixing, providing a clean interface between the liquids from the impinging jets. We also show, using the example of the luminol CL reaction, how this setup can be used to obtain kinetics information from friction-less flow and by circumventing the requirement for rapid mixing by intentionally suppressing all turbulent mixing and instead relying on diffusion.

  • Files
  • Details
  • Metrics
Loading...
Thumbnail Image
Name

jacs.2c01232.pdf

Type

Publisher

Version

http://purl.org/coar/version/c_970fb48d4fbd8a85

Access type

openaccess

License Condition

CC BY-NC-ND

Size

2.53 MB

Format

Adobe PDF

Checksum (MD5)

078341d41f7bc312e37e081a54691293

Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés