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research article

Impact of rapid thermal processing on bulk and surface recombination mechanisms in FZ silicon with fired passivating contacts

Haug, F-J  
•
Libraro, S.
•
Lehmann, M.
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May 1, 2022
Solar Energy Materials And Solar Cells

We investigate bulk and interface recombination in crystalline silicon with p-type fired passivating contacts. These consist of a chemical oxide and an in-situ doped layer of SiCx with low carbon content. Following a rapid thermal annealing to activate the dopants in the SiCx layer, we observe the formation of bulk defect states close to one of the band edges at temperatures between 450 and 700 degrees C. At temperatures of 800 degrees C and above, these bulk defects are increasingly cured. At the same time, the surface passivation provided by the interfacial oxide is increasingly deteriorated at temperatures above 800 degrees C, eventually permitting the injection of a recombination current into the SiCx layer. Consequently, there is a trade-off for the effective minority carrier lifetime with an optimum between 800 and 830 degrees C. We develop a formalism that distinguishes recombination through shallow bulk defects from the recombination current at the surface in a plot of the effective lifetime tau(eff) over the ratio n/p.

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Type
research article
DOI
10.1016/j.solmat.2022.111647
Web of Science ID

WOS:000761250300004

Author(s)
Haug, F-J  
•
Libraro, S.
•
Lehmann, M.
•
Morisset, A.
•
Ingenito, A.
•
Ballif, C.  
Date Issued

2022-05-01

Publisher

ELSEVIER

Published in
Solar Energy Materials And Solar Cells
Volume

238

Article Number

111647

Subjects

Energy & Fuels

•

Materials Science, Multidisciplinary

•

Physics, Applied

•

Materials Science

•

Physics

•

poly-si/siox contact

•

sicy/siox contact

•

ag screen-printing

•

blistering

•

pecvd si-rich sicy

•

parameters

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
PV-LAB  
Available on Infoscience
March 28, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/186612
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