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research article
Vanadium complexes with N-heterocyclic vinylidene ligands
The preparation and the structural characterization of vanadium complexes with terminal and bridging N-heterocyclic vinylidene ligands is reported. The synthesis of the complexes was enabled by utilization of diazoolefins as ligand precursors. Structural data and theoretical results show that N-heterocyclic vinylidenes can act as 6e− donor ligands, leading to strong metal–carbon interactions.
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Accepted Manuscript Not Edited.pdf
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postprint
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openaccess
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851.05 KB
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7df3cf01f9da24c6797d2695c6253317