Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer
Barluzzi, Luciano; Jori, Nadir; Maron, Laurent; Scopelliti, Rosario; Oyala, Paul; Agapie, Theodor; He, Tianyi; Rajeshkumar, Thayalan; Mazzanti, Marinella
2022

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Abstract

The reaction of a terminal Mo(II) nitride with a U(III) complex yields an heterodimetallic U-Mo nitride which is the first example of a transition metal-capped uranium nitride. The nitride is triply bonded to U(V) and singly bonded to Mo(0) and supports a U-Mo interaction. This compound shows reactivity toward CO oxidation.

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Title Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer
Author(s) Barluzzi, Luciano ; Jori, Nadir ; Maron, Laurent ; Scopelliti, Rosario ; Oyala, Paul ; Agapie, Theodor ; He, Tianyi ; Rajeshkumar, Thayalan ; Mazzanti, Marinella
Published in Chemical Communications
Volume 58
Issue 29
Pages 4655-4658
Date 2022-03-10
DOI https://doi.org/10.1039/D2CC00473A
Laboratories GCC
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > GCC - Group of Coordination Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Grant FNS: 200021_178793
Record creation date 2022-03-10

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