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  4. Implementation and understanding of p plus fired rear hole selective tunnel oxide passivating contacts enabling > 22% conversion efficiency in p-type c-Si solar cells
 
research article

Implementation and understanding of p plus fired rear hole selective tunnel oxide passivating contacts enabling > 22% conversion efficiency in p-type c-Si solar cells

Ingenito, Andrea  
•
Libraro, Sofia  
•
Wyss, Philippe  
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January 1, 2021
Solar Energy Materials And Solar Cells

Passivating contacts are key enablers for high efficiency c-Si solar cells. Here, we present our latest advancement in terms of implementation and understanding in fired passivating contacts (FPC) used as rear p + passivating contact in p-type solar cells. We study three different layer configurations and show that the microstructural layer properties play a major role on the surface passivation and charge carrier transport. Upon optimization we demonstrate implied open circuit voltage of 722 mV corresponding to saturation current density of -7 fA/cm(2) and contact resistances below 10 m Omega cm(2), when metallized with ITO/Ag. P-type c-Si solar cells employing a screen-printed P-diffused emitter co-fired with the FPC on the rear side with conversion efficiency up to 22.5% are demonstrated. Temperature-dependent measurements on test structures and solar cells reveal that tunneling is the main transport mechanism for FPC layers that crystallize during the firing process, whereas for more amorphous FPC layers, an additional component due to thermionic emission is also present. Finally, we present the efficiency potential of solar cells employing the developed FPC layer as hole selective rear side passivating contact.

  • Details
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Type
research article
DOI
10.1016/j.solmat.2020.110809
Web of Science ID

WOS:000591689000005

Author(s)
Ingenito, Andrea  
Libraro, Sofia  
Wyss, Philippe  
Allebe, Christophe
Despeisse, Matthieu  
Nicolay, Sylvain  
Haug, Franz-Josef  
Ballif, Christophe  
Date Issued

2021-01-01

Publisher

ELSEVIER

Published in
Solar Energy Materials And Solar Cells
Volume

219

Article Number

110809

Subjects

Energy & Fuels

•

Materials Science, Multidisciplinary

•

Physics, Applied

•

Materials Science

•

Physics

•

passivating contacts

•

solar cells

•

fired passivating contacts

•

upgraded perc

•

poly-si

•

lifetime

•

layers

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
PV-LAB  
Available on Infoscience
June 19, 2021
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/179015
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