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  4. A Magic Angle Spinning Activated O-17 DNP Raser
 
research article

A Magic Angle Spinning Activated O-17 DNP Raser

Hope, Michael A.
•
Bjorgvinsdottir, Snaedis  
•
Grey, Clare P.
Show more
January 14, 2021
The Journal of Physical Chemistry Letters

In the raser effect, a sample spontaneously emits continuous radiofrequency radiation, allowing exceptionally narrow NMR line widths to be recorded without applying pulses. To achieve this phenomenon, a large negative magnetization must be induced, which we show here can be achieved for the O-17 magnetization of isotopically labeled Gd-doped CeO2 using solid effect dynamic nuclear polarization (DNP), at high field and 110 K. This allows a 2 mHz line width to be measured, which is limited only by the magnetic field stability. The raser effect can be reversibly activated and deactivated by magic angle spinning (MAS), which modulates the nuclear spin coherence lifetime. The use of MAS DNP to enable the raser effect should be further applicable to other systems and nuclei.

  • Details
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Type
research article
DOI
10.1021/acs.jpclett.0c03457
Web of Science ID

WOS:000611422600001

Author(s)
Hope, Michael A.
Bjorgvinsdottir, Snaedis  
Grey, Clare P.
Emsley, Lyndon  
Date Issued

2021-01-14

Published in
The Journal of Physical Chemistry Letters
Volume

12

Issue

1

Start page

345

End page

349

Subjects

Chemistry, Physical

•

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Physics, Atomic, Molecular & Chemical

•

Chemistry

•

Science & Technology - Other Topics

•

Materials Science

•

Physics

•

nuclear

•

he-3

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LRM  
FunderGrant Number

FNS

200020_178860

Available on Infoscience
March 26, 2021
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/176376
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