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research article

Crystal electric field excitations in the quantum spin liquid candidate NaErS2

Gao, Shang
•
Xiao, Fan
•
Kamazawa, Kazuya
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July 16, 2020
Physical Review B

The delafossite family of compounds with a triangular lattice of rare earth ions has been recently proposed as a candidate host for quantum spin liquid (QSL) states. To realize QSLs, the crystal electric field (CEF) ground state of the rare earth ions should be composed of a doublet that allows sizable quantum tunneling, but until now the knowledge on CEF states in the delafossite compounds is still limited. Here we employ inelastic neutron scattering (INS) to study the CEF transitions in a powder sample of the delafossite NaErS2, where the large total angular momentum J = 15/2 of the Er3+ ions and the resulting plethora of CEF transitions enable an accurate fit of the CEF parameters. Our study reveals nearly isotropic spins with large J(z) = +/- 1/2 components for the Er3+ CEF ground states, which might facilitate the development of a QSL state. The scaling of the obtained CEF Hamiltonian to different rare earth ions suggests that sizable J(z) = +/- 1/2 components are generally present in the CEF ground states, supporting the ternary sulfide delafossites as potential QSL hosts.

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Type
research article
DOI
10.1103/PhysRevB.102.024424
Web of Science ID

WOS:000590514900001

Author(s)
Gao, Shang
Xiao, Fan
Kamazawa, Kazuya
Ikeuchi, Kazuhiko
Biner, Daniel
Kramer, Karl W.
Ruegg, Christian  
Arima, Taka-hisa
Date Issued

2020-07-16

Publisher

AMER PHYSICAL SOC

Published in
Physical Review B
Volume

102

Issue

2

Article Number

024424

Subjects

Materials Science, Multidisciplinary

•

Physics, Applied

•

Physics, Condensed Matter

•

Materials Science

•

Physics

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LUQ  
Available on Infoscience
December 3, 2020
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/173847
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