Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Hot-Hole versus Hot-Electron Transport at Cu/GaN Heterojunction Interfaces
 
research article

Hot-Hole versus Hot-Electron Transport at Cu/GaN Heterojunction Interfaces

Tagliabue, Giulia  
•
DuChene, Joseph S.
•
Habib, Adela
Show more
May 26, 2020
Acs Nano

Among all plasmonic metals, copper (Cu) has the greatest potential for realizing optoelectronic and photochemical hot-carrier devices, thanks to its CMOS compatibility and outstanding catalytic properties. Yet, relative to gold (Au) or silver (Ag), Cu has rarely been studied and the fundamental properties of its photo-excited hot carriers are not well understood. Here, we demonstrate that Cu nanoantennas on p-type gallium nitride (p-GaN) enable hot-hole-driven photo-detection across the visible spectrum. Importantly, we combine experimental measurements of the internal quantum efficiency (IQE) with ab initio theoretical modeling to clarify the competing roles of hot-carrier energy and mean-free path on the performance of hot-hole devices above and below the interband threshold of the metal. We also examine Cu-based plasmonic photodetectors on corresponding n-type GaN substrates that operate via the collection of hot electrons. By comparing hot hole and hot electron photodetectors that employ the same metal/semiconductor interface (Cu/GaN), we further elucidate the relative advantages and limitations of these complementary plasmonic systems. In particular, we find that harnessing hot holes with p-type semiconductors is a promising strategy for plasmon-driven photodetection across the visible and ultraviolet regimes. Given the technological relevance of Cu and the fundamental insights provided by our combined experimental and theoretical approach, we anticipate that our studies will have a broad impact on the design of hot-carrier optoelectronic devices and plasmon-driven photocatalytic systems.

  • Details
  • Metrics
Type
research article
DOI
10.1021/acsnano.0c00713
Web of Science ID

WOS:000537682300063

Author(s)
Tagliabue, Giulia  
DuChene, Joseph S.
Habib, Adela
Sundararaman, Ravishankar
Atwater, Harry A.
Date Issued

2020-05-26

Publisher

AMER CHEMICAL SOC

Published in
Acs Nano
Volume

14

Issue

5

Start page

5788

End page

5797

Subjects

Chemistry, Multidisciplinary

•

Chemistry, Physical

•

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Chemistry

•

Science & Technology - Other Topics

•

Materials Science

•

plasmonics

•

hot carriers

•

photodetection

•

hot holes

•

p-type gan

•

copper

•

photodetection

•

nanoparticles

•

nanocrystals

•

responsivity

•

gold

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LNET  
Available on Infoscience
June 21, 2020
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/169518
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés