The use of cellular ceramics in enhancing the performance of a high-temperature latent heat thermal energy storage unit was investigated. A detailed design methodology is presented, which consists of a combined analytical-numerical analysis followed by a multi-objective optimization. This optimization indicated that within the selected design space, effectiveness values as large as 0.95 and energy densities as large as 810 MJ/m3 could be achieved. Motivated by the results of this study, new porous structures were investigated. As the classical computer aided design tools are not optimized for quick and efficient design of cellular structures with large number of geometrical features, new design approaches were presented: two methods to design structured and unstructured lattices and a Voronoi-based design approach to create structures consisting of different unit-cells combined together. We then used a combined experimental-numerical approach to investigate the effect of the cell morphology on the heat and mass transport behavior of the porous structures. Different morphologies, namely tetrakaidecahedron, Weaire-Phelan, rotated cube and random foam, were investigated. These structures were designed in cylindrical forms, 3D printed and then manufactured in SiSiC via replica technique followed by silicon reactive infiltration. Permeability and Forchheimer coefficients of the structures were experimentally measured by pressure drop tests at room temperature. The volumetric convective heat transfer coefficients were estimated using temperature measurements and fitting a thermal non-equilibrium heat and fluid flow model to these experiments. It was observed that for the same porosity and cell density the cubic lattice and the random foam exhibited lower pressure drops but also lower heat transfer rates. Undesirable manufacturing anomalies such as pore clogging, was observed for tetrakaidecahedron and Weaire-Phelan structures, which led to a tortuosity larger than calculated, causing additional pressure drop. Finally, the mechanical and degradation behavior of five SiSiC cellular structures, namely simple cube, rotated cube, tetrakaidecahedron, modified octet-truss and random foam, was experimentally investigated in early stage oxidation conditions at 1400 °C. The samples were oxidized in two different environments: in a radiant burner and inside an electric furnace. The results revealed different mechanisms, namely silicon alloy bead formation and H2O/CO2-based corrosion, simultaniously degrading the specimens. It is shown that different lattice architectures led to different oxidation behavior on the struts resulting from the changing gas flow paths inside each ceramic architecture. The effect of the morphology on the elastic behavior of lattice structures was studied in more detail by adapting a numerical approach consisting of a unit-cell model with periodic boundaries. The elastic anisotropies of the lattices were explored by calculating the elastic modulus in different directions. The results revealed that all the studied lattices, and in particular the cubic lattice, have an anisotropic elastic behavior. A new strategy is presented to obtain unit-cells with high elastic modulus and controled anisotropy.