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  4. Thermodynamic Modeling Suggests Declines in Water Uptake and Acidity of Inorganic Aerosols in Beijing Winter Haze Events during 2014/2015-2018/2019
 
research article

Thermodynamic Modeling Suggests Declines in Water Uptake and Acidity of Inorganic Aerosols in Beijing Winter Haze Events during 2014/2015-2018/2019

Song, Shaojie
•
Nenes, Athanasios  
•
Gao, Meng
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December 1, 2019
Environmental Science & Technology Letters

During recent years, aggressive air pollution mitigation measures in northern China have resulted in considerable changes in gas and aerosol chemical composition. But it is unclear whether aerosol water content and acidity respond to these changes. The two parameters have been shown to affect heterogeneous production of winter haze aerosols. Here, we performed thermodynamic equilibrium modeling using chemical and meteorological data observed in urban Beijing for four recent winter seasons and quantified the changes in the mass growth factor and pH of inorganic aerosols. We focused on high relative humidity (>60%) conditions when submicron particles have been shown to be in the liquid state. From 2014/2015 to 2018/2019, the modeled mass growth factor decreased by about 9%-17% due to changes in aerosol compositions (more nitrate and less sulfate and chloride), and the modeled pH increased by about 0.3-0.4 unit mainly due to rising ammonia. A buffer equation is derived from semivolatile ammonia partitioning, which helps understand the sensitivity of pH to meteorological and chemical variables. The findings provide implications for evaluating the potential chemical feedback in secondary aerosol production and the effectiveness of ammonia control as a measure to alleviate winter haze.

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Type
research article
DOI
10.1021/acs.estlett.9b00621
Web of Science ID

WOS:000502418500012

Author(s)
Song, Shaojie
Nenes, Athanasios  
Gao, Meng
Zhang, Yuzhong
Liu, Pengfei
Shao, Jingyuan
Ye, Dechao
Xu, Weiqi
Lei, Lu
Sun, Yele
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Date Issued

2019-12-01

Publisher

AMER CHEMICAL SOC

Published in
Environmental Science & Technology Letters
Volume

6

Issue

12

Start page

752

End page

760

Subjects

Engineering, Environmental

•

Environmental Sciences

•

Engineering

•

Environmental Sciences & Ecology

•

atmospheric ammonia sources

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air-quality improvement

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fine-particle ph

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northern china

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anthropogenic emissions

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n-15-stable isotope

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urban-environment

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episodes evidence

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major sources

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liquid water

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LAPI  
Available on Infoscience
December 29, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/164234
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