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  4. Kinetics and Mechanism of Metal Nanoparticle Growth via Optical Extinction Spectroscopy and Computational Modeling: The Curious Case of Colloidal Gold
 
research article

Kinetics and Mechanism of Metal Nanoparticle Growth via Optical Extinction Spectroscopy and Computational Modeling: The Curious Case of Colloidal Gold

Andalibi, M. Reza  
•
Wokaun, Alexander
•
Bowen, Paul  
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2019
ACS Nano

An overarching computational framework unifying several optical theories to describe the temporal evolution of gold nanoparticles (GNPs) during a seeded growth process is presented. To achieve this, we used the inexpensive and widely available optical extinction spectroscopy, to obtain quantitative kinetic data. In situ spectra collected over a wide set of experimental conditions were regressed using the physical model, calculating light extinction by ensembles of GNPs during the growth process. This model provides temporal information on the size, shape, and concentration of the particles and any electromagnetic interactions between them. Consequently, we were able to describe the mechanism of GNP growth and divide the process into distinct genesis periods. We provide explanations for several longstanding mysteries, for example, the phenomena responsible for the purple-greyish hue during the early stages of GNP growth, the complex interactions between nucleation, growth, and aggregation events, and a clear distinction between agglomeration and electromagnetic interactions. The presented theoretical formalism has been developed in a generic fashion so that it can readily be adapted to other nanoparticulate formation scenarios such as the genesis of various metal nanoparticles.

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Type
research article
DOI
10.1021/acsnano.9b04981
Web of Science ID

WOS:000492801600061

Author(s)
Andalibi, M. Reza  
Wokaun, Alexander
Bowen, Paul  
Testino, Andrea
Date Issued

2019

Published in
ACS Nano
Volume

13

Issue

10

Start page

11510

End page

11521

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GR-LUD  
Available on Infoscience
November 19, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/163207
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