Spin-Dependent Processes at Electrodes Detected by Simultaneously Performed EPR, Electrochemistry and EDMR
The electrically detected magnetic resonance (EDMR) results presented in this thesis demonstrate
a spin dependence of the charge transfer between an electrode and an electrolyte. These results
were found using simultaneous detection of continuous wave electron paramagnetic resonance
(CW EPR), EDMR and cyclic voltammetry. The electrochemical cell was located inside a microwave
cavity and the electrolyte was saturated withmethyl viologen radicals.
Electrodes were either spin polarized using optical spin-pumping in p-GaAs or electrodes functionalized
with chiral self-assembled monolayers. Sample preparation and characterization are
presented in depth. The measurement and evaluation schemes for combined cyclic voltammogram
sweeps and stepwise magnetic field scans are discussed. The resulting detection of spin
dependent charge transfer at a spin polarized electrode/electrolyte interface is demonstrated and
quantified. The magnitude of this effect is compared with the one observed when using chiral
molecules. This brings confirmation of a chirality induced spin selectivity (CISS) effect, based on
an experiment in which the spins are excited selectively by magnetic resonance.
EPFL_TH9547.pdf
openaccess
52.6 MB
Adobe PDF
768b1c92d2adc5e1f6f8d5c31828d118