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  4. Universal Oxide Shell Growth Enables in Situ Structural Studies of Perovskite Nanocrystals during the Anion Exchange Reaction
 
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research article

Universal Oxide Shell Growth Enables in Situ Structural Studies of Perovskite Nanocrystals during the Anion Exchange Reaction

Loiudice, Anna  
•
Strach, Michal  
•
Saris, Seryio  
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May 22, 2019
Journal Of The American Chemical Society

The ability to tune thin oxide coatings by wet-chemistry is desirable for many applications, yet it remains a key synthetic challenge. In this work, we introduce a general colloidal atomic layer deposition (c-ALD) synthesis to grow an alumina shell with tunable thickness around nanocrystalline cores of various compositions spanning from ionic semiconductors (i.e., CsPbX3, with X = Br, I, Cl) to metal oxides and metals (i.e., CeO2 and Ag). The distinctive characteristics of each core (i.e., emission, facile surface functionalization, stability) allowed us to optimize and to elucidate the chemistry of the c-ALD process. Compared to gas-phase ALD, this newly developed synthesis has the advantage of preserving the colloidal stability of the nanocrystalline core while controlling the shell thickness from 1 to 6 nm. As one example of the opportunities offered by the growth of a thin oxide shell, we study the anion exchange reaction in the CsPbX3 perovskites nanocrystals by in situ X-ray diffraction, which had been impeded so far by the instability of this class of materials and by the fast exchange kinetics.

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Type
research article
DOI
10.1021/jacs.9b02061
Web of Science ID

WOS:000469292300034

Author(s)
Loiudice, Anna  
•
Strach, Michal  
•
Saris, Seryio  
•
Chernyshov, Dmitry
•
Buonsanti, Raffaella  
Date Issued

2019-05-22

Publisher

AMER CHEMICAL SOC

Published in
Journal Of The American Chemical Society
Volume

141

Issue

20

Start page

8254

End page

8263

Subjects

Chemistry, Multidisciplinary

•

Chemistry

•

cesium lead halide

•

high-efficiency

•

cation-exchange

•

quantum dots

•

surface

•

silica

•

stabilization

•

nanoparticles

•

diffusion

•

catalysts

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LNCE  
Available on Infoscience
June 18, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/157072
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