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  4. The needle model: A new model for the main hydration peak of alite
 
research article

The needle model: A new model for the main hydration peak of alite

Ouzia, Alexandre  
•
Scrivener, Karen  
January 1, 2019
Cement and Concrete Research

This article presents a new model for the main hydration peaks of tricalcium silicate and alite on the assumption that C-S-H nucleates and grows as needles. The model relies only on directly observable quantities and reproduces the transition from the acceleration to deceleration periods without assuming a diffusion barrier or impingement. Simulations of the model based on measured characteristics of the grains and needles are compared with experimental data and satisfactory agreement is found across a wide range of experiments. Because the model disentangles the impact of each input parameter, it sheds new light on some aspects of alite hydration. In particular, the model provides a quantification of the impact of the consumption of the small grains and shows that it should not be neglected as soon as several tens of percent of the hydration reaction is reached. Finally, the article provides a critical examination of other models.

  • Details
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Type
research article
DOI
10.1016/j.cemconres.2018.08.005
Web of Science ID

WOS:000452935100030

Author(s)
Ouzia, Alexandre  
Scrivener, Karen  
Date Issued

2019-01-01

Publisher

Pergamon-Elsevier Science Ltd

Published in
Cement and Concrete Research
Volume

115

Start page

339

End page

360

Subjects

Construction & Building Technology

•

Materials Science, Multidisciplinary

•

Materials Science

•

alite

•

c3s

•

hydration

•

modelling

•

c-s-h needles/fibrils

•

portland-cement

•

phase-change

•

kinetics

•

silicate

•

growth

•

nucleation

•

microstructure

•

temperature

•

morphology

•

simulation

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LMC  
Available on Infoscience
January 24, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/154067
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