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  4. Slow CH3NH3+ Diffusion in CH3NH3PbI3 under Light Measured by Solid-State NMR and Tracer Diffusion
 
research article

Slow CH3NH3+ Diffusion in CH3NH3PbI3 under Light Measured by Solid-State NMR and Tracer Diffusion

Senocrate, Alessandro
•
Moudrakovski, Igor
•
Acartuerk, Tolga
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September 27, 2018
Journal Of Physical Chemistry C

We investigate methylammonium (MA) transport in MA lead iodide under illumination and show this, as in the dark, to be measurable but negligible when compared with the major carriers. H-1 and C-13 nuclear magnetic resonance (NMR) spectra show constant linewidths as a function of temperature, indicating the absence of significant MA diffusion. C-13 tracer-exchange experiments reveal two distinct diffusion processes, one attributed to bulk MA transport and the other most probably due to higher dimensional defects. The former process has a diffusion coefficient that is consistent with the upper limit extracted from NMR measurements. Derived bulk conductivities for MA cations are orders of magnitude below the experimental ionic conductivity, corroborating the picture of pure iodine transport under illumination, as it was previously experimentally shown only for the dark situation.

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Type
research article
DOI
10.1021/acs.jpcc.8b06814
Web of Science ID

WOS:000446141900012

Author(s)
Senocrate, Alessandro
Moudrakovski, Igor
Acartuerk, Tolga
Merkle, Rotraut
Kim, Gee Yeong
Starke, Ulrich
Graetzel, Michael  
Maier, Joachim
Date Issued

2018-09-27

Publisher

AMER CHEMICAL SOC

Published in
Journal Of Physical Chemistry C
Volume

122

Issue

38

Start page

21803

End page

21806

Subjects

Chemistry, Physical

•

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Chemistry

•

Science & Technology - Other Topics

•

Materials Science

•

perovskite solar-cells

•

methylammonium lead iodide

•

halide perovskites

•

cation dynamics

•

ion conduction

•

hysteresis

•

migration

•

spectroscopy

•

coefficients

•

sensitizers

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
December 13, 2018
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/152340
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