Loading...
research article
From isonitrile to nitrile via ketenimine intermediate: Palladium-catalyzed 1,1-carbocyanation of ally carbonate by alpha-isocyanoacetate
December 6, 2018
A palladium-catalyzed 1,1-carbocyanation of allyl carbonate by alpha-quaternary alpha-isocyanoacetate was developed. Formation of ketenimine followed by homolysis of the C-N bond and recombination of the resulting caged radical pair was proposed to account for the formation of the unusual coupling product, the beta-cyano-gamma,delta-unsaturated ester. (C) 2018 Elsevier Ltd. All rights reserved.
Use this identifier to reference this record
Type
research article
Web of Science ID
WOS:000451103900002
Authors
Publication date
2018-12-06
Publisher
Published in
Volume
74
Issue
49
Start page
6966
End page
6971
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
December 13, 2018