research article
Versatile palladium-catalyzed double carbonylation of aryl bromides
A versatile palladium-catalyzed double carbonylation of aryl bromides has been developed. Using Pd(OAc)2/BuPAd2 as the catalyst system and DBU as the base, under relatively low CO pressure, various a-ketoamides were produced in good yields. In order to get insight into the reaction pathway, real time NMR studies were performed as well and a correlated reaction mechanism is been given.
Type
research article
Web of Science ID
WOS:000415661300009
Author(s)
Date Issued
2017
Publisher
Published in
Volume
53
Start page
12422
End page
12425
Editorial or Peer reviewed
REVIEWED
Written at
EPFL
EPFL units
Available on Infoscience
November 11, 2017
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