Leaching from Palladium Nanoparticles in an Ionic Liquid Leads to the Formation of Ionic Monometallic Species
2017
Abstract
Molecular dynamics simulations and DFT calculations suggest that leaching of palladium species from Pd nanoparticles in ionic liquids does not involve "naked" Pd(0) atoms or neutral ArPdX species formed by oxidative addition of arylhalides. Instead, the ionic liquid contributes largely to leaching of ionic PdX- or PdAr+ species.
Details
Title
Leaching from Palladium Nanoparticles in an Ionic Liquid Leads to the Formation of Ionic Monometallic Species
Author(s)
Zvereva, Elena E. ; Katsyuba, Sergey A. ; Dyson, Paul J. ; Aleksandrov, Alexey V.
Published in
Journal Of Physical Chemistry Letters
Pagination
5
Volume
8
Issue
15
Pages
3452-3456
Date
2017
Publisher
Washington, Amer Chemical Soc
ISSN
1948-7185
Other identifier(s)
View record in Web of Science
Laboratories
LCOM
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCOM - Laboratory of Organometallic and Medicinal Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2017-09-05