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research article

Options and limitations for bromate control during ozonation of wastewater

Soltermann, Fabian
•
Abegglen, Christian
•
Tschui, Manfred
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2017
Water Research

Wastewater treatment plants (WWTPs) are important point sources for micropollutants, which are harmful to freshwater organisms. Ozonation of wastewater is a powerful option to abate micropollutants, but may result in the formation of the potentially toxic oxidation by-product bromate in bromide containing wastewaters. This study investigates options to reduce bromate formation during wastewater ozonation by (i) reducing the bromide concentration of the wastewater, (ii) lowering the ozone dose during wastewater treatment and (iii) adding hydrogen peroxide to limit the lifetime of ozone and quench the intermediates of the bromate formation pathway. Two examples demonstrate that a high share of bromide in wastewater can originate from single point sources (e.g., municipal waste incinerators or landfills). The identification of major point sources requires laborious sampling campaigns, but may facilitate the reduction of the bromide load significantly. To reduce the bromate formation by lowering the ozone dose interferes with the aim to abate micropollutants. Therefore, an additional treatment is necessary to ensure the elimination of micropollutants. Experiments at a pilot-plant illustrate that a combined treatment (ozone/powdered activated carbon) allows to eliminate micropollutants with low bromate yields. Furthermore, the addition of hydrogen peroxide was investigated at bench scale. The bromate yields could be reduced by similar to 50% and 65% for a hydrogen peroxide dose of 5 and 10 mg L-1, respectively. In conclusion, there are options to reduce the bromate formation during wastewater ozonation, however, they are not simple with sometimes limited efficiency. (C) 2017 Elsevier Ltd. All rights reserved.

  • Details
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Type
research article
DOI
10.1016/j.watres.2017.02.026
Web of Science ID

WOS:000401208300008

Author(s)
Soltermann, Fabian
Abegglen, Christian
Tschui, Manfred
Stahel, Sandro
Von Gunten, Urs  
Date Issued

2017

Publisher

Pergamon-Elsevier Science Ltd

Published in
Water Research
Volume

116

Start page

76

End page

85

Subjects

Bromide

•

Bromate

•

Ozonation

•

Wastewater treatment

•

Micropollutants

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LTQE  
Available on Infoscience
July 10, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/139066
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