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  4. Post-test Analysis on a Solid Oxide Cell Stack Operated for 10,700 Hours in Steam Electrolysis Mode
 
research article

Post-test Analysis on a Solid Oxide Cell Stack Operated for 10,700 Hours in Steam Electrolysis Mode

Rinaldi, Giorgio  
•
Diethelm, Stefan  
•
Oveisi, Emad  
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2017
Fuel Cells

A solid oxide short stack composed of 6 Ni-YSZ supported cells, YSZ electrolyte and GDC-LSC oxygen electrode has been tested for 10,700 hours in steam electrolysis. Initial degradation was followed by a global stabilization of the performance after lowering the current density, with a degradation rate below 0.5% kh(-1). Post-test analysis has been conducted on two repeating units (RUs) to highlight the most significant microstructure alterations. Nickel depletion was observed in the hydrogen electrode close to the interface with the electrolyte. Formation of small pores in the electrolyte was detected along the grain boundaries. A consequent detachment related to this phenomenon was observed in proximity of the GDC compatibility layer. At the oxygen electrode side, the formation of a approximate to 1 mu m dense mixed layer of GDC and YSZ was observed. Strontium from the LSC electrode migrated through GDC pores and reacted with YSZ, forming evident SrZrO3 inclusions. Distinct accumulation of silicon at the Ni/YSZ interface and chromium on the GDC barrier layer have been observed in both RUs. Despite this range of alterations observed, the stack degradation remained limited, testified from the fact that performance decay between 4,000 and 10,000 hours of operation was virtually nil.

  • Details
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Type
research article
DOI
10.1002/fuce.201600194
Web of Science ID

WOS:000408318300013

Author(s)
Rinaldi, Giorgio  
Diethelm, Stefan  
Oveisi, Emad  
Burdet, Pierre  
Van Herle, Jan  
Montinaro, Dario
Fu, Qingxi
Date Issued

2017

Published in
Fuel Cells
Volume

17

Issue

4

Start page

541

End page

549

Subjects

Degradation

•

Long-term Test

•

Post-test Analysis

•

Solid Oxide Electrolysis Cell (SOEC)

•

Steam Electrolysis

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

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SCI-STI-JVH  
Available on Infoscience
June 10, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/138199
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