Synthesis and SMM behaviour of trinuclear versus dinuclear 3d-5f uranyl(v)-cobalt(II) cation-cation complexes

Trinuclear versus dinuclear heterodimetallic (UO2+)-O-V center dot center dot center dot Co2+ complexes were selectively assembled via a cation-cation interaction by tuning the ligand. The trimeric complex 2, with a linear [Co-OvUvO-Co] core, exhibits magnetic exchange and slow relaxation with a reversal barrier of 30.5 +/- 0.9 K providing the first example of a U-Co exchange-coupled SMM.


Published in:
Dalton Transactions, 46, 17, 5498-5502
Year:
2017
Publisher:
Cambridge, Royal Society of Chemistry
ISSN:
1477-9226
Laboratories:




 Record created 2017-05-30, last modified 2018-09-13


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