Hg(II) coordination complexes containing the tris(2-pyridylmethyl) amine ligand: Synthesis, characterization and crystal structure analysis
Hajiashrafi, Taraneh; Ziarani, Ghodsi Mohammadi; Kubicki, Maciej; Fadaei, Farzaneh T.; Schenk, Kurt J.
2016

Abstract

Two new Hg(II) coordination compounds containing the tris(2-pyridylmethyl)amine (TPA) ligand were synthesized by conventional and sonochemical methods, characterized by spectroscopic techniques (FT-IR and elemental analysis) and their X-ray crystallographic structures were determined. The crystal packing and supramolecular features of these coordination compounds were studied using geometrical analysis and Hirshfeld surface analysis. BFDH analysis helps us to compare the predicted morphology with that obtained under ultrasonic irradiation. This study may provide further insight into discovering the role of weak intermolecular interactions in the context of nano-coordination chemistry. (C) 2016 Elsevier Ltd. All rights reserved.

Details

Title Hg(II) coordination complexes containing the tris(2-pyridylmethyl) amine ligand: Synthesis, characterization and crystal structure analysis
Author(s) Hajiashrafi, Taraneh ; Ziarani, Ghodsi Mohammadi ; Kubicki, Maciej ; Fadaei, Farzaneh T. ; Schenk, Kurt J.
Published in Polyhedron
Pagination 7
Volume 119
Pages 260-266
Date 2016
Publisher Oxford, Elsevier
ISSN 0277-5387
Keywords
DOI https://doi.org/10.1016/j.poly.2016.09.015
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Laboratories LQM
Record Appears in Scientific production and competences > SB - School of Basic Sciences > IPHYS - Institute of Physics > LQM - Laboratory for Quantum Magnetism
Peer-reviewed publications
Work produced at EPFL
Journal Articles
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Record creation date 2017-01-24