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  4. Evolution of the Valley Position in Bulk Transition-Metal Chalcogenides and Their Monolayer Limit
 
research article

Evolution of the Valley Position in Bulk Transition-Metal Chalcogenides and Their Monolayer Limit

Yuan, Hongtao
•
Liu, Zhongkai
•
Xu, Gang
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2016
Nano Letters

Layered transition metal chalcogenides with large spin orbit coupling have recently sparked much interest due to their potential applications for electronic, optoelectronic, spintronics, and valleytronics. However, most current understanding of the electronic structure near band valleys in momentum space is based on either theoretical investigations or optical measurements, leaving the detailed band structure elusive. For example, the exact position of the conduction band valley of bulk MoS2 remains controversial. Here, using angle resolved photoemission spectroscopy with submicron spatial resolution (micro-ARPES), we systematically imaged the conduction/valence band structure evolution across representative chalcogenides MoS2, WS2, and WSe2, well as the thickness dependent electronic structure from bulk to the monolayer limit. These results establish a solid basis to understand the underlying valley physics of these materials, and also provide a link between chalcogenide electronic band structure and their physical properties for potential valleytronics applications.

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Type
research article
DOI
10.1021/acs.nanolett.5b05107
Web of Science ID

WOS:000381331900002

Author(s)
Yuan, Hongtao
Liu, Zhongkai
Xu, Gang
Zhou, Bo
Wu, Sanfeng
Dumcenco, Dumitru  
Yan, Kai
Zhang, Yi
Mo, Sung-Kwan
Dudin, Pavel
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Date Issued

2016

Publisher

American Chemical Society

Published in
Nano Letters
Volume

16

Issue

8

Start page

4738

End page

4745

Subjects

angle-resolved photoemission spectroscopy

•

band structure

•

transition metal dichalcogenides

•

valleytronics

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
IEL  
Available on Infoscience
October 18, 2016
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/130426
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