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  4. Quantification of Valleys of Randomly Textured Substrates as a Function of Opening Angle: Correlation to the Defect Density in Intrinsic nc-Si:H
 
research article

Quantification of Valleys of Randomly Textured Substrates as a Function of Opening Angle: Correlation to the Defect Density in Intrinsic nc-Si:H

Kim, Do Yun
•
Hanni, Simon
•
Schuttauf, Jan-Willem
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2016
ACS Applied Materials & Interfaces

Optical and electrical properties of hydrogenated nanocrystalline silicon (nc-Si:H) solar cells are strongly influenced by the morphology of underlying substrates. By texturing the substrates, the photogenerated current of nc-Si:H solar cells can increase due to enhanced light scattering. These textured substrates are, however, often incompatible with defect-less nc-Si:H growth resulting in lower Vo. and FF. In this study we investigate the correlation between the substrate morphology, the nc-Si:H solar-cell performance, and the defect density in the intrinsic layer of the solar cells (i-nc-Si:H). Statistical surface parameters representing the substrate morphology do not show a strong correlation with the solar-cell parameters. Thus, we first quantify the line density of potentially defective valleys of randomly textured ZnO substrates where the opening angle is smaller than 130 degrees (rho(<130)). This rho(<130) is subsequently compared with the solar-cell performance and the defect density of i-nc-Si:H (rho(defect)), which is obtained by fitting external photovoltaic parameters from experimental results and simulations. We confirm that when rho(<130) increases the V-oc and FF significantly drops. It is also observed that rho(defect) increases following a power law dependence of rho(<130). This result is attributed to more frequently formed defective regions for substrates having higher rho(<130).

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Type
research article
DOI
10.1021/acsami.6b03995
Web of Science ID

WOS:000381715900018

Author(s)
Kim, Do Yun
Hanni, Simon
Schuttauf, Jan-Willem
Van Swaaij, Rene A. C. M. M.
Zeman, Miro
Date Issued

2016

Publisher

Amer Chemical Soc

Published in
ACS Applied Materials & Interfaces
Volume

8

Issue

32

Start page

20660

End page

20666

Subjects

morphology

•

defective valleys

•

opening angle

•

defect density

•

nc-Si:H

•

simulation

•

solar cell

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
IMT  
Available on Infoscience
October 18, 2016
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/130333
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