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research article
Kinetic isotope effects for fast deuterium and proton exchange rates
By monitoring the effect of deuterium decoupling on the decay of transverse N-15 magnetization in D-N-15 spin pairs during multiple-refocusing echo sequences, we have determined fast D-D exchange rates k(D) and compared them with fast H-H exchange rates k(H) in tryptophan to determine the kinetic isotope effect as a function of pH and temperature.
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P404-Canet-Mammoli-Kaderavek-Pelupessy-Bodenhausen-Kinetic-Isotope-Effects-PCCP-18-10144-2016.pdf
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openaccess
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2.07 MB
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Adobe PDF
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1343619b899e678d5eb2eb225390f1e0
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Name
P404a_Communique_Presse_Structure_Dynamique_Biomolecules_Avril_2016.pdf
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openaccess
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428.39 KB
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Adobe PDF
Checksum (MD5)
42bfe11b68c9389feac8bae8d8bdd51e