Kinetic isotope effects for fast deuterium and proton exchange rates
Canet, Estel; Mammoli, Daniele; Kaderavek, Pavel; Pelupessy, Philippe; Bodenhausen, Geoffrey
2016
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Abstract

By monitoring the effect of deuterium decoupling on the decay of transverse N-15 magnetization in D-N-15 spin pairs during multiple-refocusing echo sequences, we have determined fast D-D exchange rates k(D) and compared them with fast H-H exchange rates k(H) in tryptophan to determine the kinetic isotope effect as a function of pH and temperature.

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Title Kinetic isotope effects for fast deuterium and proton exchange rates
Author(s) Canet, Estel ; Mammoli, Daniele ; Kaderavek, Pavel ; Pelupessy, Philippe ; Bodenhausen, Geoffrey
Published in Physical Chemistry Chemical Physics
Pagination 8
Volume 18
Issue 15
Pages 10144-10151
Date 2016
Publisher Cambridge, Royal Society of Chemistry
ISSN 1463-9076
DOI https://doi.org/10.1039/c5cp07459b
Other identifier(s) View record in Web of Science
Laboratories LRMB
Record Appears in Scientific production and competences > SB - School of Basic Sciences > SB Archives > LRMB - Laboratory of Biomolecular Magnetic Resonance
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2016-07-19

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