Loading...
research article
Thiazolium carbene catalysts for the fixation of CO2 onto amines
The catalytic N-formylation and N-methylation of amines using CO2 as the carbon source represents a facile and sustainable approach for the synthesis of pharmaceuticals and natural products. Herein, we describe highly effective and inexpensive thiazolium carbene-based catalysts derived from vitamin B1 for the N-formylation and N-methylation of amines, using polymethylhydrosiloxane (PMHS) as a reducing agent, which operate under ambient conditions.
Loading...
Name
Thiazolium carbene catalysts for the fixation of CO2 onto amines.pdf
Access type
openaccess
License Condition
CC BY
Size
1.68 MB
Format
Adobe PDF
Checksum (MD5)
e9d0cc37d1b04d37262225a166cb9815