Molecularly Defined Nanostructures Based on a Novel AAA-DDD Triple Hydrogen Bonding Motif

A facile and flexible method for the synthesis of a new AAA–DDD triple hydrogen-bonding motif is described. Polytopic supramolecular building blocks with precisely oriented AAA and DDD groups are thus accessible in few steps. These building blocks were used for the assembly of large macrocycles featuring four AAA–DDD interactions and a macrobicyclic complex with a total of six AAA–DDD interactions.


Published in:
Angewandte Chemie -International Edition in English-, 55, 1685-1689
Year:
2016
Publisher:
Weinheim, Wiley-Blackwell
ISSN:
1433-7851
Keywords:
Laboratories:


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 Record created 2016-02-09, last modified 2018-10-01

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