Efficient heteronuclear decoupling by quenching rotary resonance in solid-state NMR

We propose a new scheme for heteronuclear decoupling designed for fast magic-angle spinning (MAS), dubbed phase-inverted supercycled sequence for attenuation of rotary resonance (PISSARRO). Its efficiency compares favourably with CW, TPPM, SPINAL and XiX decoupling methods at medium and high RF amplitudes, particularly under conditions where the efficiency of decoupling is affected by undesired rotary resonance effects.


Published in:
Chemical Physics Letters, 466, 4-6, 247-251
Year:
2008
Publisher:
Elsevier
ISSN:
0009-2614
Laboratories:




 Record created 2015-12-22, last modified 2018-09-13


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