Journal article

Inhomogeneity of charge-density-wave order and quenched disorder in a high-T-c superconductor

It has recently been established that the high-transition-temperature (high-T-c) superconducting state coexists with short-range charge-density-wave order(1-11) and quenched disorder(12,13) arising from dopants and strain(14-17). This complex, multiscale phase separation(18-21) invites the development of theories of high-temperature superconductivity that include complexity(22-25). The nature of the spatial interplay between charge and dopant order that provides a basis for nanoscale phase separation remains a key open question, because experiments have yet to probe the unknown spatial distribution at both the nanoscale and mesoscale (between atomic and macroscopic scale). Here we report micro X-ray diffraction imaging of the spatial distribution of both short-range charge-density-wave 'puddles' (domains with only a few wavelengths) and quenched disorder in HgBa2CuO4+y, the single-layer cuprate with the highest T-c, 95 kelvin (refs 26-28). We found that the charge-density-wave puddles, like the steam bubbles in boiling water, have a fat-tailed size distribution that is typical of self-organization near a critical point(19). However, the quenched disorder, which arises from oxygen interstitials, has a distribution that is contrary to the usually assumed random, uncorrelated distribution(12,13). The interstitial-oxygen-rich domains are spatially anticorrelated with the charge-density-wave domains, because higher doping does not favour the stripy charge-density-wave puddles, leading to a complex emergent geometry of the spatial landscape for superconductivity.


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