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research article

Structural, electrical and magnetic characterization of in-situ crystallized ZnO:Co thin films synthesized by reactive magnetron sputtering

Lardjane, Soumia
•
Yazdi, Mohammad Arab Pour
•
Martin, Nicolas
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2015
Materials Chemistry And Physics

Zn1-xCoxO (0 < x < 0.146) conductive thin films have been deposited by reactive magnetron sputtering of metallic Zn and Co targets at high pressure and temperature. The structural properties have been investigated by using X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). It has been observed that all as-deposited films are crystallized in pure hcp ZnO structure and neither traces of metallic nor oxide Co-rich clusters were detected. The average grain size estimated from full width at half maximum of XRD results varied between 65 and 83 nm. XPS analyses exhibit that Co ions are successfully entered into ZnO lattice as Co. The electrical properties including conductivity, carrier density and carrier mobility were determined by Hall effect measurements in a temperature range from 300 K to 475 K. The conductivity of the films decreases from sigma(300K) = 2.2 x 10(4) to 2.3 x 10(-1) Sm-1 as the Co content changes from 0 to 0.146. Magnetic measurements reveal the absence of ferromagnetism even at 3 K and a paramagnetic Curie-Weiss behavior associated to magnetic clusters. (C) 2015 Elsevier B.V. All rights reserved.

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Type
research article
DOI
10.1016/j.matchemphys.2015.04.037
Web of Science ID

WOS:000357139600004

Author(s)
Lardjane, Soumia
Yazdi, Mohammad Arab Pour
Martin, Nicolas
Bellouard, Christine
Fenineche, Nour-Eddine
Schueler, Andreas  
Merad, Ghouti
Billard, Alain
Date Issued

2015

Publisher

Elsevier Science Sa

Published in
Materials Chemistry And Physics
Volume

161

Start page

26

End page

34

Subjects

Thin films

•

Semiconductors

•

Physical vapor deposition (PVD)

•

Electrical properties

•

Magnetic properties

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LESO-PB  
Available on Infoscience
September 28, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/119009
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