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  4. Neutral, polaron, and bipolaron states in PEDOT prepared by photoelectrochemical polymerization and the effect on charge generation mechanism in the solid-state dye-sensitized solar cell
 
research article

Neutral, polaron, and bipolaron states in PEDOT prepared by photoelectrochemical polymerization and the effect on charge generation mechanism in the solid-state dye-sensitized solar cell

Park, Byung-wook
•
Yang, Lei
•
Johansson, Erik M. J.
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2013
Journal of Physical Chemistry C

We investigate dye-sensitized solar cells (DSSCs) based on PEDOT as hole conductor and prepd. by photoelectrochem. polymer deposition at different light intensities. We specifically investigate the effect of light intensity on the PEDOT polymer and in turn the efficiency of the solar cells. We find that the PEDOT prepd. by this method is largely oxidized and contains significant amts. of polarons and bipolarons and only a small fraction of neutral PEDOT. Photoelectrochem. polymer deposition under low light intensity leads to a particularly low fraction of neutral PEDOT and a high fraction of bipolarons as measured in the UV-vis spectra. The solar cells based on PEDOT as a hole conductor prepd. under these conditions are the most efficient with a higher power conversion efficiency, which can be explained by a longer electron lifetime, faster charge transport, and higher transparency of the PEDOT. Interestingly, we conclude that in this type of solid-state DSSCs the mechanism of dye regeneration occurs from PEDOT polarons that then form bipolarons, which is different from the mechanism of dye regeneration proposed in std. solid-state DSSCs.

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Type
research article
DOI
10.1021/jp406493v
Author(s)
Park, Byung-wook
Yang, Lei
Johansson, Erik M. J.
Vlachopoulos, Nick  
Chams, Amani
Perruchot, Christian
Jouini, Mohamed
Boschloo, Gerrit
Hagfeldt, Anders  
Date Issued

2013

Published in
Journal of Physical Chemistry C
Volume

117

Start page

22484

End page

22491

Subjects

polaron bipolaron PEDOT photoelectrochem polymn

•

solid state dye sensitized solar cell

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LSPM  
Available on Infoscience
July 6, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/115887
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