Influence of π-Conjugation Units in Organic Dyes for Dye-Sensitized Solar Cells

Two org. dyes with the general structure donor-conjugated chain-acceptor (D-π-A) were studied as sensitizers for nanocryst. TiO2 solar cells. The electron donor and acceptor groups were pyrrolidine and cyano acrylic acid, resp. The conjugated chain of 2-cyano-3-{5-[2-(4-pyrrolidin-1-ylphenyl)vinyl]thiophen-2-yl}acrylic acid contains one Ph ring and a thiophene unit and is therefore denoted PT, while for 2-cyano-3-{5-[2-(5-pyrrolidin-1-ylthiophen-2-yl)vinyl]thiophen-2-yl}acrylic acid the Ph ring is replaced by a 2nd thiophene unit (TT). Solar-to-elec. energy conversion efficiencies under simulated AM 1.5 irradn. (1000 W m-2) of 2.3% were obtained for solar cells based on PT but of <0.05% for those based on TT. The reasons for the dramatic difference of the efficiencies were analyzed. Photoinduced absorption measurements revealed that the TT dye was not properly regenerated by redox electrolyte after electron injection. This sluggish regeneration is probably due to the 0.3 V less pos. HOMO level for TT dye compared to the PT dye, resulting in a lower driving force for regeneration of the oxidized dye by iodide in the electrolyte. Regeneration of the oxidized TT dye and electron injection from the excited TT dye may be poor due to formation of dye aggregates/complexes, as FTIR measurements show an excess of not properly and/or unidentate bound TT dye mols. instead of bidentate bound PT dye mols. The results highlight that small structural change of dyes results in significant changes in redox energies and binding features, affecting dramatically the performance of these dyes in dye-sensitized solar cells.

Published in:
Journal of Physical Chemistry C, 111, 1853-1860

 Record created 2015-07-06, last modified 2018-03-17

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