Loading...
Determination of sample temperature in unstable static fields by combining solid-state Br-79 and C-13 NMR
research article
Monitoring the isotropic chemical shifts to calibrate the sample temperature presupposes a perfect stability of the static magnetic field. It can be difficult to satisfy this requirement in solid-state NMR measurements. This paper describes a simple way to recover the accurate temperature dependence of the 79Br resonance after subtracting changes of resonance frequency due to variations of the static field, monitored by the 13C resonance. © 2014 Elsevier Inc. All rights reserved.
Loading...
Name
P379-Purusottam-Bodenhausen-Tekely-Temperature-Unstable-Fields-JMR-246-69-2014.pdf
Access type
openaccess
Size
605.66 KB
Format
Adobe PDF
Checksum (MD5)
c4163d9192964f6adff4a973e29415bb