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  4. NMR MEASUREMENT OF RESOLVED HETERONUCLEAR DIPOLE COUPLINGS IN LIQUID-CRYSTALS AND LIPIDS
 
research article

NMR MEASUREMENT OF RESOLVED HETERONUCLEAR DIPOLE COUPLINGS IN LIQUID-CRYSTALS AND LIPIDS

SCHMIDT-ROHR, K
•
NANZ, D
•
EMSLEY, L  
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1994
The Journal of Physical Chemistry (1952 - 1996)

Simplified nuclear magnetic resonance (NMR) spectra of heteronuclear dipolar couplings for molecules in an anisotropic environment, such as liquid crystals and lipids, are obtained by proton-detected local-field spectroscopy. The distance-dependent dipolar interactions between spins of magnetically active nuclei can be determined directly from the spectrum because many-body effects that complicate conventional dipolar NMR spectra are avoided by selectively probing local fields produced by rare spins at the location of abundant spins. We employ the technique to resolve the carbon-proton dipolar couplings of benzene dissolved in a nematic liquid crystal and to measure phosphorus-proton couplings in lecithin in the L(alpha) phase to obtain constraints on the phosphocholine headgroup structure.

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Type
research article
DOI
10.1021/j100078a002
Author(s)
SCHMIDT-ROHR, K
NANZ, D
EMSLEY, L  
PINES, A
Date Issued

1994

Publisher

AMER CHEMICAL SOC

Published in
The Journal of Physical Chemistry (1952 - 1996)
Volume

98

Issue

27

Start page

6668

End page

6670

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LRM  
Available on Infoscience
January 8, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/110171
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