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research article

High-resolution NMR correlation spectra of disordered solids

Sakellariou, D
•
Brown, SP
•
Lesage, A
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2003
Journal of the American Chemical Society

We show how high-resolution NMR spectra can be obtained for solids for which the spectra are normally broadened due to structural disorder. The method relies on correlations in the chemical shifts between pairs of coupled spins. It is found experimentally that there are strong correlations in the chemical shifts between neighboring spins in both phosphorus-31 and carbon-13 spectra. These correlations can be exploited not only to provide resolution in two-dimensional spectra, but also to yield ``chains'' of correlated chemical shifts, constituting a valuable new source of structural information for disordered materials.

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Type
research article
DOI
10.1021/ja0292389
Web of Science ID

WOS:000182003500067

Author(s)
Sakellariou, D
Brown, SP
Lesage, A
Hediger, S
Bardet, M
Meriles, CA
Pines, A
Emsley, L  
Date Issued

2003

Publisher

AMER CHEMICAL SOC

Published in
Journal of the American Chemical Society
Volume

125

Issue

14

Start page

4376

End page

4380

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LRM  
Available on Infoscience
January 8, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/110111
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