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research article

Experimental aspects of proton NMR spectroscopy in solids using phase-modulated homonuclear dipolar decoupling

Lesage, A
•
Sakellariou, D
•
Hediger, S
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2003
Journal of Magnetic Resonance

In this paper we demonstrate experimentally that the continuously phase-modulated homonuclear decoupling sequence DUMBO-1 is suitable for high-resolution proton NMR spectroscopy of rigid solids. Over a wide range of experimental conditions, we show on the model sample L-alanine as well as on small peptides that proton linewidths of less than 0.5 ppm can be obtained under DUMBO-1 decoupling. In particular the DUMBO-1 sequence yields well resolved proton spectra both at slow and fast MAS. The DUMBO-1 decoupling scheme can in principle be inserted in any multi-nuclear or multi-dimensional solid-state NMR experiment which requires a high-resolution H-1 dimension. An example is provided with the C-13-H-1 MAS-J-HMQC experiment. (C) 2003 Elsevier Science (USA). All rights reserved.

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Type
research article
DOI
10.1016/S1090-7807(03)00104-6
Web of Science ID

WOS:000184278600013

Author(s)
Lesage, A
Sakellariou, D
Hediger, S
Elena, B
Charmont, P
Steuernagel, S
Emsley, L  
Date Issued

2003

Publisher

Academic Press Inc - Elsevier Science

Published in
Journal of Magnetic Resonance
Volume

163

Issue

1

Start page

105

End page

113

Subjects

solid-state proton spectroscopy

•

high-field NMR

•

homonuclear decoupling

•

fast MAS

•

heteronuclear spectroscopy

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LRM  
Available on Infoscience
January 8, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/110109
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