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  4. The performance of phase modulated heteronuclear dipolar decoupling schemes in fast magic-angle-spinning nuclear magnetic resonance experiments
 
research article

The performance of phase modulated heteronuclear dipolar decoupling schemes in fast magic-angle-spinning nuclear magnetic resonance experiments

De Paepe, G
•
Lesage, A
•
Emsley, L  
2003
Journal of Chemical Physics

The experimental performance of the phase modulated decoupling schemes SDROOPY-1 and SPINAL64 is investigated for heteronuclear dipolar decoupling in solid-state magic-angle-spinning nuclear magnetic resonance (NMR), in comparison with existing decoupling methods. It is found that both sequences perform well over a range of spinning rates from 0 to 35 kHz, with linewidths that are virtually independent of the spinning rate. The signal intensity is found to diminish with increasing spinning rate, and this behavior is compared qualitatively with theory. It is also demonstrated that decoupling sequences strongly influence the refocused linewidths observed in solid-state NMR, and that SDROOPY-1 and SPINAL64 both yield particularly long dephasing times. (C) 2003 American Institute of Physics.

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Type
research article
DOI
10.1063/1.1595088
Web of Science ID

WOS:000184775200027

Author(s)
De Paepe, G
Lesage, A
Emsley, L  
Date Issued

2003

Publisher

AMER INST PHYSICS

Published in
Journal of Chemical Physics
Volume

119

Issue

9

Start page

4833

End page

4841

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LRM  
Available on Infoscience
January 8, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/110106
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