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research article

Direct spectral optimisation of proton-proton homonuclear dipolar decoupling in solid-state NMR

Elena, B
•
de Paepe, G
•
Emsley, L  
2004
Chemical Physics Letters

We show how direct spectral optimisation can be used to provide significantly improved resolution for proton NMR spectroscopy in the solid state. We describe the design of new continuous phase modulated schemes for proton-proton homonuclear dipolar decoupling, exploiting an experimental optimisation procedure through observation of carbon-13 lineshapes. The performance of the resulting eDUMBO homonuclear decoupling sequences is demonstrated with a variety of high resolution proton NMR experiments at 500 and 700 MHz, and at different magic angle spinning speeds. (C) 2004 Elsevier B.V. All rights reserved.

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Type
research article
DOI
10.1016/j.cplett.2004.09.122
Web of Science ID

WOS:000224852800047

Author(s)
Elena, B
de Paepe, G
Emsley, L  
Date Issued

2004

Publisher

Elsevier

Published in
Chemical Physics Letters
Volume

398

Issue

4-6

Start page

532

End page

538

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LRM  
Available on Infoscience
January 8, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/110094
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