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research article
Powder crystallography by proton solid-state NMR spectroscopy
The investigation of H-1-H-1 spin-diffusion build-up curves using a rate matrix analysis approach shows that high-resolution magic angle spinning NMR of protons, applied to powdered organic compounds, provides a method to probe crystalline arrangements. The comparison between experimental H-1 data and simulation is shown to depend strongly on the parameters of the crystal structure, for example on the unit cell parameters or the orientation of the molecule in the unit cell, and those parameters are experimentally determined for a model organic compound.
Type
research article
Web of Science ID
WOS:000230010600055
Authors
Publication date
2005
Publisher
Published in
Volume
127
Issue
25
Start page
9140
End page
9146
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
January 8, 2015
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