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  4. Absence of curie relaxation in paramagnetic solids yields long H-1 coherence lifetimes
 
research article

Absence of curie relaxation in paramagnetic solids yields long H-1 coherence lifetimes

Kervern, Gwendal
•
Steuernagel, Stefan
•
Engelke, Frank
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2007
Journal of the American Chemical Society

NMR of paramagnetic systems in solution is hampered by relaxation enhancement (PRE). Here we present a method to access paramagnetic line widths in microcrystalline samples under magic angle spinning. We demonstrate that a CPMG technique may advantageously be combined with fast MAS of paramagnetic solids and suitable adiabatic pulses both to provide increased sensitivity and to allow experimental determination of the homogeneous coherence lifetimes T (2)'. In this way, we show that the Curie contribution to PRE is absent in solids and, therefore, that the lifetimes of nuclear coherences may be longer than in liquids for paramagnetic systems, even for protons.

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Type
research article
DOI
10.1021/ja075319z
Web of Science ID

WOS:000251182000007

Author(s)
Kervern, Gwendal
Steuernagel, Stefan
Engelke, Frank
Pintacuda, Guido
Emsley, Lyndon  
Date Issued

2007

Publisher

AMER CHEMICAL SOC

Published in
Journal of the American Chemical Society
Volume

129

Issue

46

Start page

14118

End page

14119

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LRM  
Available on Infoscience
January 8, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/110062
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