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research article
Synthesis and reactivity of molybdenum imido alkylidene bis-pyrazolide complexes
2010
Reaction of Li(3,5-R(2)-pyrazolide) (R = tBu or Ph, dXpz) with Mo(NAr)(CHCMe(2)Ph)(OTf)(2)(DME) yields Mo(NAr)(CHCMe(2)Ph)(dXpz)(2) in good yield. These complexes react with alcohols or the surface silanols of silica, to yield bis-alkoxy and surface mono-siloxy alkene metathesis catalysts, respectively.
Type
research article
Web of Science ID
WOS:000281605800024
Authors
Gajan, David
•
Rendon, Nuria
•
Wampler, Keith M.
•
Basset, Jean-Marie
•
Coperet, Christophe
•
Lesage, Anne
•
•
Schrock, Richard R.
Publication date
2010
Publisher
Published in
Volume
39
Issue
36
Start page
8547
End page
8551
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
January 8, 2015
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