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  4. Homonuclear dipolar decoupling with very large scaling factors for high-resolution ultrafast magic angle spinning H-1 solid-state NMR spectroscopy
 
research article

Homonuclear dipolar decoupling with very large scaling factors for high-resolution ultrafast magic angle spinning H-1 solid-state NMR spectroscopy

Salager, Elodie
•
Dumez, Jean-Nicolas
•
Stein, Robin S.
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2010
Chemical Physics Letters

We present a new phase modulated radio-frequency pulse sequence for homonuclear dipolar decoupling in proton solid-state NMR spectroscopy, eDUMBO-PLUS-1, with a chemical shift scaling factor of 0.73. This sequence was determined by screening random sequences, and experimentally optimizing the best candidates directly on H-1 NMR spectra with 60 kHz magic angle spinning. It yields efficient decoupling with linewidths as little as 150 Hz for 1.3 mm MAS probes on different spectrometers. Experiments and calculations support the hypothesis of a radio-frequency and MAS joint averaging regime, in which the large scaling factor contributes significantly to the overall performance of the decoupling sequence. (C) 2010 Elsevier B. V. All rights reserved.

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Type
research article
DOI
10.1016/j.cplett.2010.08.038
Web of Science ID

WOS:000282161800041

Author(s)
Salager, Elodie
Dumez, Jean-Nicolas
Stein, Robin S.
Steuernagel, Stefan
Lesage, Anne
Elena-Herrmann, Benedicte
Emsley, Lyndon  
Date Issued

2010

Publisher

Elsevier

Published in
Chemical Physics Letters
Volume

498

Issue

1-3

Start page

214

End page

220

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LRM  
Available on Infoscience
January 8, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/110017
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