Probing surface site heterogeneity through 1D and INADEQUATE P-31 solid state NMR spectroscopy of silica supported PMe3-Au(I) adducts
Gajan, David; Levine, Daniel; Zocher, Eva; Coperet, Christophe; Lesage, Anne; Emsley, Lyndon
2011

Abstract

Grafting of (Me3Si)(2)N-AuPMe3 on SiO2-(700) leads to the formation of [( SiO)Au-PMe3] located in different surface environments due to the presence or absence of adjacent siloxane bridges, as shown both by P-31 solid state NMR and by its conversion into a mixture of [( SiO)Au-PMe3] and [( SiO)Au(PMe3)(2)] upon exposure to PMe3.

Details

Title Probing surface site heterogeneity through 1D and INADEQUATE P-31 solid state NMR spectroscopy of silica supported PMe3-Au(I) adducts
Author(s) Gajan, David ; Levine, Daniel ; Zocher, Eva ; Coperet, Christophe ; Lesage, Anne ; Emsley, Lyndon
Published in CHEMICAL SCIENCE
Volume 2
Issue 5
Pages 928-931
Date 2011
Publisher ROYAL SOC CHEMISTRY
ISSN 2041-6520
DOI https://doi.org/10.1039/c0sc00579g
Other identifier(s) View record in Web of Science
Laboratories LRM
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LRM - Laboratory of Magnetic Resonance
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date 2015-01-08