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  4. Improved Phase-Modulated Homonuclear Dipolar Decoupling for Solid-State NMR Spectroscopy from Symmetry Considerations
 
research article

Improved Phase-Modulated Homonuclear Dipolar Decoupling for Solid-State NMR Spectroscopy from Symmetry Considerations

Halse, Meghan E.
•
Emsley, Lyndon  
2013
The Journal of Physical Chemistry A

We explore the effects of symmetry on the performance of phase-modulated homonuclear dipolar decoupling in H-1 solid-state NMR. We demonstrate that the symmetry of the DUMBO family of decoupling sequences is the result of two well-defined symmetry expansions. The first is an antipalindromic expansion that arises from the symmetrization step that was built into the original architecture of the DUMBO sequence. The second is a mirror-pair expansion that inverts the sign of the phase modulation in the second half of the pulse sequence relative to the first. The combination of these two symmetry expansions generates a sequence of four Lee-Goldburg-type rotations in the rotating frame. The axes of rotation, oriented at the magic angle, are separated in the transverse plane by 2 alpha, where alpha is chosen to minimize the sensitivity of the sequence to instrument imperfections such as rf inhomogeneity. The efficiency of the DUMBO symmetry for decoupling is demonstrated experimentally, and the effect of the alpha-phase-shift parameter is investigated. A new decoupling sequence (LG4) that combines the DUMBO symmetry with alpha = 55 degrees is introduced and is shown to produce very efficient decoupling as well as a nearly 2-fold increase in coherence lifetimes when compared to standard PMLG/FSLG decoupling.

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Type
research article
DOI
10.1021/jp4038733
Web of Science ID

WOS:000321236700007

Author(s)
Halse, Meghan E.
Emsley, Lyndon  
Date Issued

2013

Publisher

AMER CHEMICAL SOC

Published in
The Journal of Physical Chemistry A
Volume

117

Issue

25

Start page

5280

End page

5290

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LRM  
Available on Infoscience
January 8, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/109971
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