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research article

A hybrid absorption-adsorption method to efficiently capture carbon

Liu, Huang
•
Liu, Bei
•
Lin, Li-Chiang
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2014
Nature Communications

Removal of carbon dioxide is an essential step in many energy-related processes. Here we report a novel slurry concept that combines specific advantages of metal-organic frameworks, ion liquids, amines and membranes by suspending zeolitic imidazolate framework-8 in glycol-2-methylimidazole solution. We show that this approach may give a more efficient technology to capture carbon dioxide compared to conventional technologies. The carbon dioxide sorption capacity of our slurry reaches 1.25 mol l(-1) at 1 bar and the selectivity of carbon dioxide/hydrogen, carbon dioxide/nitrogen and carbon dioxide/methane achieves 951, 394 and 144, respectively. We demonstrate that the slurry can efficiently remove carbon dioxide from gas mixtures at normal pressure/temperature through breakthrough experiments. Most importantly, the sorption enthalpy is only -29 kJ mol(-1), indicating that significantly less energy is required for sorbent regeneration. In addition, from a technological point of view, unlike solid adsorbents slurries can flow and be pumped. This allows us to use a continuous separation process with heat integration.

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Type
research article
DOI
10.1038/ncomms6147
Web of Science ID

WOS:000343980700011

Author(s)
Liu, Huang
Liu, Bei
Lin, Li-Chiang
Chen, Guangjin
Wu, Yuqing
Wang, Jin
Gao, Xueteng
Lv, Yining
Pan, Yong
Zhang, Xiaoxin
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Date Issued

2014

Publisher

Nature Publishing Group

Published in
Nature Communications
Volume

5

Article Number

5147

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSMO  
Available on Infoscience
December 30, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/109836
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