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research article
Ligand assisted cleavage of uranium oxo-clusters
Dibenzoylmethanate replaces the bridging triflate ligands in uranium triflate polyoxo-clusters and cleaves the U12O20 core yielding the new [U6O4(OH)4(η-dbm) 12] dibenzoylmethanate (dbm-) cluster which slowly dissociates into a monomeric complex. This reactivity demonstrates the importance of bridging ligands in stabilizing uranium polyoxo-clusters. © 2010 The Royal Society of Chemistry.
Type
research article
Web of Science ID
WOS:000276376000012
Authors
Publication date
2010
Published in
Volume
46
Issue
16
Start page
2757
End page
2759
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
November 7, 2014
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