New polynuclear U(IV)-U(V) complexes from U(IV) mediated uranyl(V) disproportionation

U(iv) promotes the disproportionation of otherwise stable uranyl(v) Schiff base complexes affording U(iv)-U(v) oxo clusters with new geometries and the first example of a U(iv)⋯UO 2 + cation-cation interaction.


Published in:
Chemical Communications, 48, 6, 868-870
Year:
2012
ISSN:
1359-7345
Laboratories:




 Record created 2014-11-07, last modified 2018-03-17


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