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research article
Siloxides as Supporting Ligands in Uranium(III)-Mediated Small-Molecule Activation
Siloxides can support U! in the reduction of small molecules with uranium complexes. The treatment of [UN(SiMe3)23] with HOSi(OtBu)3 (3 equiv) yielded a novel homoleptic uranium(III) siloxide complex 1, which acted as a two-electron reducing agent toward CS 2 and CO2 (see scheme). Complex 1 also reduced toluene to afford a diuranium inverted-sandwich complex. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Type
research article
Web of Science ID
WOS:000311706500025
Authors
Mougel, Victor
•
Camp, Clement
•
Pecaut, Jacques
•
Coperet, Christophe
•
Maron, Laurent
•
Kefalidis, Christos E.
•
Publication date
2012
Published in
Volume
51
Issue
49
Start page
12280
End page
12284
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
November 7, 2014
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