Base-Driven Assembly of Large Uranium Oxo/Hydroxo Clusters
Biswas, Biplab; Mougel, Victor; Pecaut, Jacques; Mazzanti, Marinella
2011

Abstract

Uranium building blocks: Two new uranium cluster topologies are obtained from the stoichiometric hydrolysis of low-valent uranium in non-aqueous media (see picture). The organic base TMEDA directs the self-assembly process towards the formation of a nanosized oxo-hydroxo U16 cluster. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Details

Title Base-Driven Assembly of Large Uranium Oxo/Hydroxo Clusters
Author(s) Biswas, Biplab ; Mougel, Victor ; Pecaut, Jacques ; Mazzanti, Marinella
Published in Angewandte Chemie-International Edition
Volume 50
Issue 25
Pages 5744-5747
Date 2011
ISSN 1433-7851
DOI https://doi.org/10.1002/anie.201101327
Other identifier(s) View record in Web of Science
Laboratories GCC
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > GCC - Group of Coordination Chemistry
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date 2014-11-07

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