Journal article

Base-Driven Assembly of Large Uranium Oxo/Hydroxo Clusters

Uranium building blocks: Two new uranium cluster topologies are obtained from the stoichiometric hydrolysis of low-valent uranium in non-aqueous media (see picture). The organic base TMEDA directs the self-assembly process towards the formation of a nanosized oxo-hydroxo U16 cluster. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


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